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Synthetically Guided Investigation of Lanthanide and Actinide Redox and Bonding Properties

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자료유형	E-Book
개인저자	Pattenaude, Scott A.
단체저자명	Purdue University. Chemistry.
서명/저자사항	Synthetically Guided Investigation of Lanthanide and Actinide Redox and Bonding Properties.
발행사항	[S.l.] : Purdue University., 2018
발행사항	Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항	185 p.
소장본 주기	School code: 0183.
ISBN	9780438018570
일반주기	Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B. Adviser: Suzanne C. Bart.
요약	The complex bonding and redox properties of actinide elements are much less understood compared to common main group and transition metal elements. This is likely the result of fewer chemical studies, due to the challenges of working with these
요약	Along these lines, the first chapter discusses the interactions of an ONO-chelating redox-active ligand with uranium. Uranium derivatives of a dioxophenoxazine ligand, (DOPOq)2UO2, (DOPOsq)UI 2(THF)2, (DOPOcat)UI(THF)2, and Cp*U(DOPOcat)(THF)2 (
요약	The second chapter describes the stability imparted by this dioxophenoxazine ligand in the formation of tris(DOPO) complexes. This chapter involves the discussion of the first non-aqueous isostructural series of coordination compounds for member
요약	The third chapter addresses subtle electronic characteristics associated with redox-active ligand uranium complexes. Uranium complexes (Mes DAE)2U(THF) (1-DAE) and Cp2U( MesDAE) (2-DAE), bearing redox-innocent alpha-diamine ligands, have been sy
요약	The fourth chapter describes the synthesis of redox-active pyridine(diimine) (PDI) lanthanide complexes with an aim to bring redox activity to the notoriously redox non active metal centers. A full reduction series of the Mes PDIMe ligated to ne
요약	The fifth chapter describes the synthesis and reactivity of new uranyl complexes containing novel alkyl amide ligands. New uranyl derivatives featuring the amide ligand, -N(SiHMe2)tBu, were synthesized and characterized by X-ray crystallography,
일반주제명	Chemistry. Inorganic chemistry.
언어	영어
기본자료 저록	Dissertation Abstracts International79-10B(E). Dissertation Abstract International
대출바로가기	http://www.riss.kr/pdu/ddodLink.do?id=T14997819