| LDR | | 02831nmm uu200457 4500 |
| 001 | | 000000332843 |
| 005 | | 20240805171707 |
| 008 | | 181129s2018 |||||||||||||||||c||eng d |
| 020 | |
▼a 9780438018570 |
| 035 | |
▼a (MiAaPQ)AAI10808496 |
| 035 | |
▼a (MiAaPQ)purdue:22702 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
| 082 | 0 |
▼a 540 |
| 100 | 1 |
▼a Pattenaude, Scott A. |
| 245 | 10 |
▼a Synthetically Guided Investigation of Lanthanide and Actinide Redox and Bonding Properties. |
| 260 | |
▼a [S.l.] :
▼b Purdue University.,
▼c 2018 |
| 260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
| 300 | |
▼a 185 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B. |
| 500 | |
▼a Adviser: Suzanne C. Bart. |
| 502 | 1 |
▼a Thesis (Ph.D.)--Purdue University, 2018. |
| 520 | |
▼a The complex bonding and redox properties of actinide elements are much less understood compared to common main group and transition metal elements. This is likely the result of fewer chemical studies, due to the challenges of working with these |
| 520 | |
▼a Along these lines, the first chapter discusses the interactions of an ONO-chelating redox-active ligand with uranium. Uranium derivatives of a dioxophenoxazine ligand, (DOPOq)2UO2, (DOPOsq)UI 2(THF)2, (DOPOcat)UI(THF)2, and Cp*U(DOPOcat)(THF)2 ( |
| 520 | |
▼a The second chapter describes the stability imparted by this dioxophenoxazine ligand in the formation of tris(DOPO) complexes. This chapter involves the discussion of the first non-aqueous isostructural series of coordination compounds for member |
| 520 | |
▼a The third chapter addresses subtle electronic characteristics associated with redox-active ligand uranium complexes. Uranium complexes (Mes DAE)2U(THF) (1-DAE) and Cp2U( MesDAE) (2-DAE), bearing redox-innocent alpha-diamine ligands, have been sy |
| 520 | |
▼a The fourth chapter describes the synthesis of redox-active pyridine(diimine) (PDI) lanthanide complexes with an aim to bring redox activity to the notoriously redox non active metal centers. A full reduction series of the Mes PDIMe ligated to ne |
| 520 | |
▼a The fifth chapter describes the synthesis and reactivity of new uranyl complexes containing novel alkyl amide ligands. New uranyl derivatives featuring the amide ligand, -N(SiHMe2)tBu, were synthesized and characterized by X-ray crystallography, |
| 590 | |
▼a School code: 0183. |
| 650 | 4 |
▼a Chemistry. |
| 650 | 4 |
▼a Inorganic chemistry. |
| 690 | |
▼a 0485 |
| 690 | |
▼a 0488 |
| 710 | 20 |
▼a Purdue University.
▼b Chemistry. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 79-10B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0183 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2018 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T14997819
▼n KERIS |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a 관리자 |