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Synthesis and Reactivity of Paramagnetic Late Transition Metal Complexes Supported by Tris(Oxazolinyl)Phenylborate

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개인저자Reinig, Regina Rose.
단체저자명Iowa State University. Chemistry.
서명/저자사항Synthesis and Reactivity of Paramagnetic Late Transition Metal Complexes Supported by Tris(Oxazolinyl)Phenylborate.
발행사항[S.l.] : Iowa State University., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항156 p.
소장본 주기School code: 0097.
ISBN9780438076877
일반주기 Source: Dissertation Abstracts International, Volume: 79-11(E), Section: B.
Adviser: Aaron D. Sadow.
요약Our group previously developed the synthesis of main group Zn(II) and Mg(II) complexes supported by the ToM (tris(4,4-dimethyl-2-oxazolinyl)phenylborate) ligand. The reactivity of these main group oxazolinyl based complexes in oxygenation, hydro
요약Salt metathesis reaction of TlToM with CoCl2&bull
요약Reaction of ToMCoCl, ToMFeBr, and To MNiCl with alkyllithiums or potassium benzyl were attempted as a route to organometallic complexes. The nickel(II) alkyls were not identified under the reaction conditions attempted
요약ToMCoR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph) complexes react with CO followed by O2 to form the carboxylate compounds ToMCoO2CR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph). The direct insertion of CO 2 into the Co-R bond is determined to be much s
일반주제명Inorganic chemistry.
언어영어
기본자료 저록Dissertation Abstracts International79-11B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T14997417

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