LDR | | 02100nmm uu200409 4500 |
001 | | 000000332509 |
005 | | 20240805170924 |
008 | | 181129s2018 |||||||||||||||||c||eng d |
020 | |
▼a 9780438076877 |
035 | |
▼a (MiAaPQ)AAI10787805 |
035 | |
▼a (MiAaPQ)iastate:17199 |
040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
082 | 0 |
▼a 546 |
100 | 1 |
▼a Reinig, Regina Rose.
▼0 (orcid)0000-0002-4379-8249 |
245 | 10 |
▼a Synthesis and Reactivity of Paramagnetic Late Transition Metal Complexes Supported by Tris(Oxazolinyl)Phenylborate. |
260 | |
▼a [S.l.] :
▼b Iowa State University.,
▼c 2018 |
260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
300 | |
▼a 156 p. |
500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-11(E), Section: B. |
500 | |
▼a Adviser: Aaron D. Sadow. |
502 | 1 |
▼a Thesis (Ph.D.)--Iowa State University, 2018. |
520 | |
▼a Our group previously developed the synthesis of main group Zn(II) and Mg(II) complexes supported by the ToM (tris(4,4-dimethyl-2-oxazolinyl)phenylborate) ligand. The reactivity of these main group oxazolinyl based complexes in oxygenation, hydro |
520 | |
▼a Salt metathesis reaction of TlToM with CoCl2&bull |
520 | |
▼a Reaction of ToMCoCl, ToMFeBr, and To MNiCl with alkyllithiums or potassium benzyl were attempted as a route to organometallic complexes. The nickel(II) alkyls were not identified under the reaction conditions attempted |
520 | |
▼a ToMCoR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph) complexes react with CO followed by O2 to form the carboxylate compounds ToMCoO2CR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph). The direct insertion of CO 2 into the Co-R bond is determined to be much s |
590 | |
▼a School code: 0097. |
650 | 4 |
▼a Inorganic chemistry. |
690 | |
▼a 0488 |
710 | 20 |
▼a Iowa State University.
▼b Chemistry. |
773 | 0 |
▼t Dissertation Abstracts International
▼g 79-11B(E). |
773 | |
▼t Dissertation Abstract International |
790 | |
▼a 0097 |
791 | |
▼a Ph.D. |
792 | |
▼a 2018 |
793 | |
▼a English |
856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T14997417
▼n KERIS |
980 | |
▼a 201812
▼f 2019 |
990 | |
▼a 관리자 |