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020 ▼a 9780438076877
035 ▼a (MiAaPQ)AAI10787805
035 ▼a (MiAaPQ)iastate:17199
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0820 ▼a 546
1001 ▼a Reinig, Regina Rose. ▼0 (orcid)0000-0002-4379-8249
24510 ▼a Synthesis and Reactivity of Paramagnetic Late Transition Metal Complexes Supported by Tris(Oxazolinyl)Phenylborate.
260 ▼a [S.l.] : ▼b Iowa State University., ▼c 2018
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2018
300 ▼a 156 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-11(E), Section: B.
500 ▼a Adviser: Aaron D. Sadow.
5021 ▼a Thesis (Ph.D.)--Iowa State University, 2018.
520 ▼a Our group previously developed the synthesis of main group Zn(II) and Mg(II) complexes supported by the ToM (tris(4,4-dimethyl-2-oxazolinyl)phenylborate) ligand. The reactivity of these main group oxazolinyl based complexes in oxygenation, hydro
520 ▼a Salt metathesis reaction of TlToM with CoCl2&bull
520 ▼a Reaction of ToMCoCl, ToMFeBr, and To MNiCl with alkyllithiums or potassium benzyl were attempted as a route to organometallic complexes. The nickel(II) alkyls were not identified under the reaction conditions attempted
520 ▼a ToMCoR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph) complexes react with CO followed by O2 to form the carboxylate compounds ToMCoO2CR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph). The direct insertion of CO 2 into the Co-R bond is determined to be much s
590 ▼a School code: 0097.
650 4 ▼a Inorganic chemistry.
690 ▼a 0488
71020 ▼a Iowa State University. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 79-11B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0097
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T14997417 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자