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Probing the Chemical Stability and Adsorption Properties of Molecule|Metal Oxide Architectures under Conditions of Photoelectrochemical Water Oxidation

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자료유형E-Book
개인저자Esarey, Samuel L.
단체저자명University of Michigan. Chemistry.
서명/저자사항Probing the Chemical Stability and Adsorption Properties of Molecule|Metal Oxide Architectures under Conditions of Photoelectrochemical Water Oxidation.
발행사항[S.l.] : University of Michigan., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항175 p.
소장본 주기School code: 0127.
ISBN9780438125568
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
Advisers: Bart Bartlett
요약Photoelectrochemical (PEC) water splitting is one viable method for harvesting and storing solar energy, serving as a benign alternative to fossil fuels as a way of powering society sustainably. It involves the conversion of water to O2 and H2 g
요약On the other hand, homogeneous water oxidation catalysts (WOCs) are much better suited to oxidize water selectively at low overpotential compared to metal oxide semiconductors. They are easily tunable based on the ligand design and can achieve h
요약Many researchers have designed devices that functionalize metal oxide photoanodes with WOCs or dyes, but they also suffer from instability of the molecular|solid-state interaction due to either anchoring group desorption or instability, and/or c
요약This thesis will quantify these phenomenon as a means of getting to the heart of the problem, in order to determine ways to improve the system. First, I explore the binding constants and adsorption/desorption kinetics associated with phosphonic
요약Finally, I discuss at the end of the thesis potential areas in which you could move forward with this information. This discussion includes the pursuit of new anchoring groups better suited for the neutral to basic regime other than hydroxamic a
일반주제명Inorganic chemistry.
언어영어
기본자료 저록Dissertation Abstracts International79-12B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T15000458

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