| LDR | | 02599nmm uu200421 4500 |
| 001 | | 000000331895 |
| 005 | | 20240805165607 |
| 008 | | 181129s2018 |||||||||||||||||c||eng d |
| 020 | |
▼a 9780438125568 |
| 035 | |
▼a (MiAaPQ)AAI10902949 |
| 035 | |
▼a (MiAaPQ)umichrackham:001262 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
| 082 | 0 |
▼a 546 |
| 100 | 1 |
▼a Esarey, Samuel L. |
| 245 | 10 |
▼a Probing the Chemical Stability and Adsorption Properties of Molecule|Metal Oxide Architectures under Conditions of Photoelectrochemical Water Oxidation. |
| 260 | |
▼a [S.l.] :
▼b University of Michigan.,
▼c 2018 |
| 260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
| 300 | |
▼a 175 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B. |
| 500 | |
▼a Advisers: Bart Bartlett |
| 502 | 1 |
▼a Thesis (Ph.D.)--University of Michigan, 2018. |
| 520 | |
▼a Photoelectrochemical (PEC) water splitting is one viable method for harvesting and storing solar energy, serving as a benign alternative to fossil fuels as a way of powering society sustainably. It involves the conversion of water to O2 and H2 g |
| 520 | |
▼a On the other hand, homogeneous water oxidation catalysts (WOCs) are much better suited to oxidize water selectively at low overpotential compared to metal oxide semiconductors. They are easily tunable based on the ligand design and can achieve h |
| 520 | |
▼a Many researchers have designed devices that functionalize metal oxide photoanodes with WOCs or dyes, but they also suffer from instability of the molecular|solid-state interaction due to either anchoring group desorption or instability, and/or c |
| 520 | |
▼a This thesis will quantify these phenomenon as a means of getting to the heart of the problem, in order to determine ways to improve the system. First, I explore the binding constants and adsorption/desorption kinetics associated with phosphonic |
| 520 | |
▼a Finally, I discuss at the end of the thesis potential areas in which you could move forward with this information. This discussion includes the pursuit of new anchoring groups better suited for the neutral to basic regime other than hydroxamic a |
| 590 | |
▼a School code: 0127. |
| 650 | 4 |
▼a Inorganic chemistry. |
| 690 | |
▼a 0488 |
| 710 | 20 |
▼a University of Michigan.
▼b Chemistry. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 79-12B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0127 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2018 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000458
▼n KERIS |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a 관리자 |