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Accessing High Oxidation State Metal Complexes with Pyridine Alkoxide Ligands
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| 자료유형 | E-Book |
|---|---|
| 개인저자 | Shopov, Dimitar Yavorov. |
| 단체저자명 | Yale University. |
| 서명/저자사항 | Accessing High Oxidation State Metal Complexes with Pyridine Alkoxide Ligands. |
| 발행사항 | [S.l.] : Yale University., 2018 |
| 발행사항 | Ann Arbor : ProQuest Dissertations & Theses, 2018 |
| 형태사항 | 370 p. |
| 소장본 주기 | School code: 0265. |
| ISBN | 9780438194816 |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
Advisers: Robert Crabtree |
| 요약 | This thesis describes work on several projects, all related to the utilization of pyridine alkoxide ligands for stabilizing transition metals in high oxidation states. The main focus is on the ligand 2-(2-pyridinyl)-2-propanolate (pyalk), a bide |
| 요약 | Driven by interest in finding a synthetic route to oxo-bridged iridium pyalk dimers to study as analogues to a highly active but structurally ambiguous water oxidation catalyst, a series of Ir(pyalk)1-3Cl4-0 complexes were prepared (Chapters 2 a |
| 요약 | The Ir(pyalk)2Cl2 complexes could then be reacted with Ag2O to give a novel class of stable Ir(IV,IV) micro-oxo dimers of the type (Ir(pyalk)2Cl)2O (Chapter 4). Like the monomers, these were redox-active, with an accessible Ir(III,III) state, bu |
| 요약 | In the course of research with pyalk, a series of dimeric and trimeric analogues of this ligand were found to form as side products during the synthesis (Chapter 5). These share the interesting properties of pyalk itself but provide tetradentate |
| 요약 | The work presented in this thesis contributes to the field of high oxidation-state coordination chemistry. Specifically, it significantly expands the understanding of iridium(IV) and iridium(V) coordination complexes, demonstrates the effectiven |
| 일반주제명 | Inorganic chemistry. Molecular chemistry. Analytical chemistry. |
| 언어 | 영어 |
| 기본자료 저록 | Dissertation Abstracts International79-12B(E). Dissertation Abstract International |
| 대출바로가기 | http://www.riss.kr/pdu/ddodLink.do?id=T15000860 |
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인쇄
| No. | 등록번호 | 청구기호 | 소장처 | 도서상태 | 반납예정일 | 예약 | 서비스 | 매체정보 |
|---|---|---|---|---|---|---|---|---|
| 1 | WE00025768 | 546 | 가야대학교// | 대출가능 |
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