| LDR | | 02574nmm uu200457 4500 |
| 001 | | 000000331441 |
| 005 | | 20240805164404 |
| 008 | | 181129s2018 |||||||||||||||||c||eng d |
| 020 | |
▼a 9780438194816 |
| 035 | |
▼a (MiAaPQ)AAI10927911 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
| 082 | 0 |
▼a 546 |
| 100 | 1 |
▼a Shopov, Dimitar Yavorov. |
| 245 | 10 |
▼a Accessing High Oxidation State Metal Complexes with Pyridine Alkoxide Ligands. |
| 260 | |
▼a [S.l.] :
▼b Yale University.,
▼c 2018 |
| 260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
| 300 | |
▼a 370 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B. |
| 500 | |
▼a Advisers: Robert Crabtree |
| 502 | 1 |
▼a Thesis (Ph.D.)--Yale University, 2018. |
| 520 | |
▼a This thesis describes work on several projects, all related to the utilization of pyridine alkoxide ligands for stabilizing transition metals in high oxidation states. The main focus is on the ligand 2-(2-pyridinyl)-2-propanolate (pyalk), a bide |
| 520 | |
▼a Driven by interest in finding a synthetic route to oxo-bridged iridium pyalk dimers to study as analogues to a highly active but structurally ambiguous water oxidation catalyst, a series of Ir(pyalk)1-3Cl4-0 complexes were prepared (Chapters 2 a |
| 520 | |
▼a The Ir(pyalk)2Cl2 complexes could then be reacted with Ag2O to give a novel class of stable Ir(IV,IV) micro-oxo dimers of the type (Ir(pyalk)2Cl)2O (Chapter 4). Like the monomers, these were redox-active, with an accessible Ir(III,III) state, bu |
| 520 | |
▼a In the course of research with pyalk, a series of dimeric and trimeric analogues of this ligand were found to form as side products during the synthesis (Chapter 5). These share the interesting properties of pyalk itself but provide tetradentate |
| 520 | |
▼a The work presented in this thesis contributes to the field of high oxidation-state coordination chemistry. Specifically, it significantly expands the understanding of iridium(IV) and iridium(V) coordination complexes, demonstrates the effectiven |
| 590 | |
▼a School code: 0265. |
| 650 | 4 |
▼a Inorganic chemistry. |
| 650 | 4 |
▼a Molecular chemistry. |
| 650 | 4 |
▼a Analytical chemistry. |
| 690 | |
▼a 0488 |
| 690 | |
▼a 0431 |
| 690 | |
▼a 0486 |
| 710 | 20 |
▼a Yale University. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 79-12B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0265 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2018 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000860
▼n KERIS |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a 관리자 |