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Application of Transition Metal Coordination for Energy Efficient Processes: Catalysis and Separation

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개인저자Shrestha, Sweta.
단체저자명The Ohio State University. Chemistry.
서명/저자사항Application of Transition Metal Coordination for Energy Efficient Processes: Catalysis and Separation.
발행사항[S.l.] : The Ohio State University., 2017
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2017
형태사항337 p.
소장본 주기School code: 0168.
ISBN9780438098183
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
Adviser: Prabir Dutta.
요약The goal of this dissertation is to explore the application of transition metals in two energy-intensive processes, photochemical water oxidation and olefin/paraffin separation. Photochemical water splitting is widely studied and involves the ex
요약Our first strategy was the deposition of birnessite on zeolite surfaces. The synthesis method involves ion-exchanging Mn2+ cations along with alkaline earth metal co-cations (M2+: Mg2+, Ca2+, Sr2+, Ba2+) into zeolite followed by the precipitatio
요약Photochemical water oxidation was performed in Ru(bpy)3 2+- persulfate system, and the dissolved oxygen evolution rate (turnover frequency: TOF) was measured. KMnOx- Y(M2+) catalysts were better than the corresponding M2+MnOx-Y. We propose that
요약The second strategy exploited the interlayer space of birnessite. Redox active iron(III) cations were ion-exchanged into the interlayer of birnessite, and referred to as Fe(IE)MnOx. We also adopted an in-situ strategy for doping Fe3+ cations int
요약Propylene/propane (PY/PP) separation is of significant industrial importance. PY/PP are separated using highly expensive cryogenic distillation, and membrane-based processes with high flux and selectivity offer an energy-efficient alternative. T
일반주제명Inorganic chemistry.
언어영어
기본자료 저록Dissertation Abstracts International79-12B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T15000303

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