MARC보기
LDR00000nmm u2200205 4500
001000000330668
00520241104131243
008181129s2017 ||| | | | eng d
020 ▼a 9780438098183
035 ▼a (MiAaPQ)AAI10901877
035 ▼a (MiAaPQ)OhioLINK:osu1502975499629018
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0491 ▼f DP
0820 ▼a 546
1001 ▼a Shrestha, Sweta.
24510 ▼a Application of Transition Metal Coordination for Energy Efficient Processes: Catalysis and Separation.
260 ▼a [S.l.] : ▼b The Ohio State University., ▼c 2017
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2017
300 ▼a 337 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
500 ▼a Adviser: Prabir Dutta.
5021 ▼a Thesis (Ph.D.)--The Ohio State University, 2017.
520 ▼a The goal of this dissertation is to explore the application of transition metals in two energy-intensive processes, photochemical water oxidation and olefin/paraffin separation. Photochemical water splitting is widely studied and involves the ex
520 ▼a Our first strategy was the deposition of birnessite on zeolite surfaces. The synthesis method involves ion-exchanging Mn2+ cations along with alkaline earth metal co-cations (M2+: Mg2+, Ca2+, Sr2+, Ba2+) into zeolite followed by the precipitatio
520 ▼a Photochemical water oxidation was performed in Ru(bpy)3 2+- persulfate system, and the dissolved oxygen evolution rate (turnover frequency: TOF) was measured. KMnOx- Y(M2+) catalysts were better than the corresponding M2+MnOx-Y. We propose that
520 ▼a The second strategy exploited the interlayer space of birnessite. Redox active iron(III) cations were ion-exchanged into the interlayer of birnessite, and referred to as Fe(IE)MnOx. We also adopted an in-situ strategy for doping Fe3+ cations int
520 ▼a Propylene/propane (PY/PP) separation is of significant industrial importance. PY/PP are separated using highly expensive cryogenic distillation, and membrane-based processes with high flux and selectivity offer an energy-efficient alternative. T
590 ▼a School code: 0168.
650 4 ▼a Inorganic chemistry.
690 ▼a 0488
71020 ▼a The Ohio State University. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 79-12B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0168
791 ▼a Ph.D.
792 ▼a 2017
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000303 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자 ▼b 관리자