LDR | | 00000nmm u2200205 4500 |
001 | | 000000330668 |
005 | | 20241104131243 |
008 | | 181129s2017 ||| | | | eng d |
020 | |
▼a 9780438098183 |
035 | |
▼a (MiAaPQ)AAI10901877 |
035 | |
▼a (MiAaPQ)OhioLINK:osu1502975499629018 |
040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
049 | 1 |
▼f DP |
082 | 0 |
▼a 546 |
100 | 1 |
▼a Shrestha, Sweta. |
245 | 10 |
▼a Application of Transition Metal Coordination for Energy Efficient Processes: Catalysis and Separation. |
260 | |
▼a [S.l.] :
▼b The Ohio State University.,
▼c 2017 |
260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2017 |
300 | |
▼a 337 p. |
500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B. |
500 | |
▼a Adviser: Prabir Dutta. |
502 | 1 |
▼a Thesis (Ph.D.)--The Ohio State University, 2017. |
520 | |
▼a The goal of this dissertation is to explore the application of transition metals in two energy-intensive processes, photochemical water oxidation and olefin/paraffin separation. Photochemical water splitting is widely studied and involves the ex |
520 | |
▼a Our first strategy was the deposition of birnessite on zeolite surfaces. The synthesis method involves ion-exchanging Mn2+ cations along with alkaline earth metal co-cations (M2+: Mg2+, Ca2+, Sr2+, Ba2+) into zeolite followed by the precipitatio |
520 | |
▼a Photochemical water oxidation was performed in Ru(bpy)3 2+- persulfate system, and the dissolved oxygen evolution rate (turnover frequency: TOF) was measured. KMnOx- Y(M2+) catalysts were better than the corresponding M2+MnOx-Y. We propose that |
520 | |
▼a The second strategy exploited the interlayer space of birnessite. Redox active iron(III) cations were ion-exchanged into the interlayer of birnessite, and referred to as Fe(IE)MnOx. We also adopted an in-situ strategy for doping Fe3+ cations int |
520 | |
▼a Propylene/propane (PY/PP) separation is of significant industrial importance. PY/PP are separated using highly expensive cryogenic distillation, and membrane-based processes with high flux and selectivity offer an energy-efficient alternative. T |
590 | |
▼a School code: 0168. |
650 | 4 |
▼a Inorganic chemistry. |
690 | |
▼a 0488 |
710 | 20 |
▼a The Ohio State University.
▼b Chemistry. |
773 | 0 |
▼t Dissertation Abstracts International
▼g 79-12B(E). |
773 | |
▼t Dissertation Abstract International |
790 | |
▼a 0168 |
791 | |
▼a Ph.D. |
792 | |
▼a 2017 |
793 | |
▼a English |
856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000303
▼n KERIS |
980 | |
▼a 201812
▼f 2019 |
990 | |
▼a 관리자
▼b 관리자 |