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Roles of Cation-macrocycle Interactions in Modulating the Reactivity of Transition Metal Pincer-crown Ether Complexes
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| 자료유형 | E-Book |
|---|---|
| 개인저자 | Smith, Jacob B. |
| 단체저자명 | The University of North Carolina at Chapel Hill. Chemistry. |
| 서명/저자사항 | Roles of Cation-macrocycle Interactions in Modulating the Reactivity of Transition Metal Pincer-crown Ether Complexes. |
| 발행사항 | [S.l.] : The University of North Carolina at Chapel Hill., 2018 |
| 발행사항 | Ann Arbor : ProQuest Dissertations & Theses, 2018 |
| 형태사항 | 191 p. |
| 소장본 주기 | School code: 0153. |
| ISBN | 9780438349568 |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Alexander J M Miller. |
| 요약 | Pincer-crown ether ligands were designed to exhibit hemilability and also support cation- macrocycle interactions. These ligands feature strong phosphine and phenyl donors, and a pendent aza-crown ether group that provides hemilabile donors that |
| 요약 | In chapter 2, nickel catalysts supported by diethylamine- or aza-crown ether-containing aminophosphinite (NCOP) pincer ligands catalyze the insertion of benzaldehyde into a C--H bond of acetonitrile. Neutral tert -butoxide precatalysts are activ |
| 요약 | In Chapter 3, the thermochemistry of cation--macrocycle interactions in nickel pincer complexes bearing a hemilabile aza-15-crown-5 or aza-18-crown-6 macrocycle is investigated and applied to cation-controlled reversible ligand binding. Cation-c |
| 요약 | In Chapter 4, the impact of post-macrocyclization modification of 1-aza-15-crown 5 through synthetic organic and organometallic tuning is discussed. Binding affinities for Li+ and Na+ salts are reduced substantially moving from the simple organi |
| 일반주제명 | Chemistry. |
| 언어 | 영어 |
| 기본자료 저록 | Dissertation Abstracts International80-01B(E). Dissertation Abstract International |
| 대출바로가기 | http://www.riss.kr/pdu/ddodLink.do?id=T14999881 |
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| No. | 등록번호 | 청구기호 | 소장처 | 도서상태 | 반납예정일 | 예약 | 서비스 | 매체정보 |
|---|---|---|---|---|---|---|---|---|
| 1 | WE00024614 | 540 | 가야대학교// | 대출가능 |
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