| LDR | | 02363nmm uu200409 4500 |
| 001 | | 000000330287 |
| 005 | | 20240805161156 |
| 008 | | 181129s2018 |||||||||||||||||c||eng d |
| 020 | |
▼a 9780438349568 |
| 035 | |
▼a (MiAaPQ)AAI10842910 |
| 035 | |
▼a (MiAaPQ)unc:18077 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
| 082 | 0 |
▼a 540 |
| 100 | 1 |
▼a Smith, Jacob B. |
| 245 | 10 |
▼a Roles of Cation-macrocycle Interactions in Modulating the Reactivity of Transition Metal Pincer-crown Ether Complexes. |
| 260 | |
▼a [S.l.] :
▼b The University of North Carolina at Chapel Hill.,
▼c 2018 |
| 260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
| 300 | |
▼a 191 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B. |
| 500 | |
▼a Adviser: Alexander J M Miller. |
| 502 | 1 |
▼a Thesis (Ph.D.)--The University of North Carolina at Chapel Hill, 2018. |
| 520 | |
▼a Pincer-crown ether ligands were designed to exhibit hemilability and also support cation- macrocycle interactions. These ligands feature strong phosphine and phenyl donors, and a pendent aza-crown ether group that provides hemilabile donors that |
| 520 | |
▼a In chapter 2, nickel catalysts supported by diethylamine- or aza-crown ether-containing aminophosphinite (NCOP) pincer ligands catalyze the insertion of benzaldehyde into a C--H bond of acetonitrile. Neutral tert -butoxide precatalysts are activ |
| 520 | |
▼a In Chapter 3, the thermochemistry of cation--macrocycle interactions in nickel pincer complexes bearing a hemilabile aza-15-crown-5 or aza-18-crown-6 macrocycle is investigated and applied to cation-controlled reversible ligand binding. Cation-c |
| 520 | |
▼a In Chapter 4, the impact of post-macrocyclization modification of 1-aza-15-crown 5 through synthetic organic and organometallic tuning is discussed. Binding affinities for Li+ and Na+ salts are reduced substantially moving from the simple organi |
| 590 | |
▼a School code: 0153. |
| 650 | 4 |
▼a Chemistry. |
| 690 | |
▼a 0485 |
| 710 | 20 |
▼a The University of North Carolina at Chapel Hill.
▼b Chemistry. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 80-01B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0153 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2018 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T14999881
▼n KERIS |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a 관리자 |