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Investigation into the Dyotropic Rearrangement of Arene-Allene Cycloadducts, Studies Toward the Synthesis of Isonitrile-Containing Diterpene Natural Products, and Synthesis of Indolines via Cobalt(III)-Carbene Radical Catalysis

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개인저자Karns, Alexander Sager.
단체저자명University of California, Irvine. Chemistry - Ph.D..
서명/저자사항Investigation into the Dyotropic Rearrangement of Arene-Allene Cycloadducts, Studies Toward the Synthesis of Isonitrile-Containing Diterpene Natural Products, and Synthesis of Indolines via Cobalt(III)-Carbene Radical Catalysis.
발행사항[S.l.] : University of California, Irvine., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항437 p.
소장본 주기School code: 0030.
ISBN9780438304178
일반주기 Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Christopher D. Vanderwal.
요약Described herein is a compilation of studies in both methodology development and total synthesis in organic chemistry. Chapter 1 describes in detail notable discoveries in the field of dyotropic rearrangements, highlighting computational investi
요약Chapter 4 discusses in detail the isocyanoterpene natural products, including their proposed biogenesis, their observed bioactivity, and synthetic strategies by which they can be obtained in a laboratory setting. Chapter 5 elaborates specificall
요약Chapter 7 describes in detail the isolation of (+)-7,20-diisocyanoadociane and summarizes the total synthesis efforts toward the completed natural product. Chapter 8 highlights our improvements to our previously published formal synthesis of DIC
요약Chapter 9 provides a short summary of the field of cobalt(III)-carbene radical catalysis, including both mechanistic studies and applications to small molecule synthesis. Chapter 10 details our application of this unique reactivity to a rapid an
일반주제명Chemistry.
언어영어
기본자료 저록Dissertation Abstracts International80-01B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T14999078

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