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Expanding the Structural Scope of Supramolecular Assemblies and Their Applications as Mechanistic Probes

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자료유형E-Book
개인저자Hong, Cynthia Marilyn.
단체저자명University of California, Berkeley. Chemistry.
서명/저자사항Expanding the Structural Scope of Supramolecular Assemblies and Their Applications as Mechanistic Probes.
발행사항[S.l.] : University of California, Berkeley., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항126 p.
소장본 주기School code: 0028.
ISBN9780438324084
일반주기 Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Advisers: F. Dean Toste
요약Chapter 1. A brief background and perspective is provided for the field of supramolecular chemistry. Justification for the continued expansion of the field as well as the work described in this dissertation are presented.
요약Chapter 2. A new synthetic strategy for the rapid diversification of M4L6 host structures is described. The outlined approach consists of two components: the first is the late-stage functionalization of a ligand precursor to access structural va
요약Chapter 3. A novel supramolecular mechanistic probe is introduced, which serves as an experimental platform for isolating and evaluating the role of host charge in supramolecular catalysis. The probe consists of two isostructural metal--ligand c
요약Chapter 4. An unusual enzyme-like mechanism of host--guest binding is described in a new metal--ligand host of Ga4L 4 stoichiometry. The introduction of a sufficiently large and tightly bound guest enforces a configurational isomerization in the
일반주제명Chemistry.
언어영어
기본자료 저록Dissertation Abstracts International80-01B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T14997867

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