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020 ▼a 9780438324084
035 ▼a (MiAaPQ)AAI10809308
035 ▼a (MiAaPQ)berkeley:17742
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0820 ▼a 540
1001 ▼a Hong, Cynthia Marilyn.
24510 ▼a Expanding the Structural Scope of Supramolecular Assemblies and Their Applications as Mechanistic Probes.
260 ▼a [S.l.] : ▼b University of California, Berkeley., ▼c 2018
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2018
300 ▼a 126 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
500 ▼a Advisers: F. Dean Toste
5021 ▼a Thesis (Ph.D.)--University of California, Berkeley, 2018.
520 ▼a Chapter 1. A brief background and perspective is provided for the field of supramolecular chemistry. Justification for the continued expansion of the field as well as the work described in this dissertation are presented.
520 ▼a Chapter 2. A new synthetic strategy for the rapid diversification of M4L6 host structures is described. The outlined approach consists of two components: the first is the late-stage functionalization of a ligand precursor to access structural va
520 ▼a Chapter 3. A novel supramolecular mechanistic probe is introduced, which serves as an experimental platform for isolating and evaluating the role of host charge in supramolecular catalysis. The probe consists of two isostructural metal--ligand c
520 ▼a Chapter 4. An unusual enzyme-like mechanism of host--guest binding is described in a new metal--ligand host of Ga4L 4 stoichiometry. The introduction of a sufficiently large and tightly bound guest enforces a configurational isomerization in the
590 ▼a School code: 0028.
650 4 ▼a Chemistry.
690 ▼a 0485
71020 ▼a University of California, Berkeley. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 80-01B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0028
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T14997867 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자