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Highly Reactive Metal Porphyrazines
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| 자료유형 | E-Book |
|---|---|
| 개인저자 | Gao, Hongxin. |
| 단체저자명 | Princeton University. Chemistry. |
| 서명/저자사항 | Highly Reactive Metal Porphyrazines. |
| 발행사항 | [S.l.] : Princeton University., 2018 |
| 발행사항 | Ann Arbor : ProQuest Dissertations & Theses, 2018 |
| 형태사항 | 249 p. |
| 소장본 주기 | School code: 0181. |
| ISBN | 9780438047488 |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Adviser: John T. Groves. |
| 요약 | Nature has evolved a variety of different metalloenzymes for the selective oxygenation of C--H bonds. Cytochrome P450s, for example, are heme proteins that use an oxoiron(IV)-porphyrin pi-radical cation to break strong C--H bonds. Lipoxygenases, |
| 요약 | Chapters 2 and 3 concentrate on a highly reactive hydroxo iron(III) porphyrazine complex, (PyPz)FeIII--OH (PyPz = tetramethyl-2,3-pyridino porphyrazine). Fe(II) and Fe(III) porphyrazines were synthesized and characterized. Electrochemical analys |
| 요약 | In chapter 4, I report the first example of a fully characterized mononuclear CoIII--OH complex which can abstract benzylic C--H bonds as strong as 82 kcal/mol. This Co(III) porphyrazine was also determined to react with hydrocarbon substrates t |
| 요약 | In the final chapter, I extend my research to manganese porphyrazine. (PyPz)Mn has more complicated oxidation states and redox properties. It can catalytically generate chlorine dioxide from chlorite at extremely fast rates with relatively high |
| 일반주제명 | Chemistry. |
| 언어 | 영어 |
| 기본자료 저록 | Dissertation Abstracts International79-10B(E). Dissertation Abstract International |
| 대출바로가기 | http://www.riss.kr/pdu/ddodLink.do?id=T14997969 |
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| No. | 등록번호 | 청구기호 | 소장처 | 도서상태 | 반납예정일 | 예약 | 서비스 | 매체정보 |
|---|---|---|---|---|---|---|---|---|
| 1 | WE00027059 | 540 | 가야대학교// | 대출가능 |
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