| LDR | | 02198nmm uu200409 4500 |
| 001 | | 000000332732 |
| 005 | | 20240805171501 |
| 008 | | 181129s2018 |||||||||||||||||c||eng d |
| 020 | |
▼a 9780438047488 |
| 035 | |
▼a (MiAaPQ)AAI10811290 |
| 035 | |
▼a (MiAaPQ)princeton:12496 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
| 082 | 0 |
▼a 540 |
| 100 | 1 |
▼a Gao, Hongxin. |
| 245 | 10 |
▼a Highly Reactive Metal Porphyrazines. |
| 260 | |
▼a [S.l.] :
▼b Princeton University.,
▼c 2018 |
| 260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
| 300 | |
▼a 249 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B. |
| 500 | |
▼a Adviser: John T. Groves. |
| 502 | 1 |
▼a Thesis (Ph.D.)--Princeton University, 2018. |
| 520 | |
▼a Nature has evolved a variety of different metalloenzymes for the selective oxygenation of C--H bonds. Cytochrome P450s, for example, are heme proteins that use an oxoiron(IV)-porphyrin pi-radical cation to break strong C--H bonds. Lipoxygenases, |
| 520 | |
▼a Chapters 2 and 3 concentrate on a highly reactive hydroxo iron(III) porphyrazine complex, (PyPz)FeIII--OH (PyPz = tetramethyl-2,3-pyridino porphyrazine). Fe(II) and Fe(III) porphyrazines were synthesized and characterized. Electrochemical analys |
| 520 | |
▼a In chapter 4, I report the first example of a fully characterized mononuclear CoIII--OH complex which can abstract benzylic C--H bonds as strong as 82 kcal/mol. This Co(III) porphyrazine was also determined to react with hydrocarbon substrates t |
| 520 | |
▼a In the final chapter, I extend my research to manganese porphyrazine. (PyPz)Mn has more complicated oxidation states and redox properties. It can catalytically generate chlorine dioxide from chlorite at extremely fast rates with relatively high |
| 590 | |
▼a School code: 0181. |
| 650 | 4 |
▼a Chemistry. |
| 690 | |
▼a 0485 |
| 710 | 20 |
▼a Princeton University.
▼b Chemistry. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 79-10B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0181 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2018 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T14997969
▼n KERIS |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a 관리자 |