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Biocatalytic Carbon Capture and Conversion

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개인저자Xia, Shunxiang.
단체저자명University of Minnesota. Biosystems and Agricultural Engineering.
서명/저자사항Biocatalytic Carbon Capture and Conversion.
발행사항[S.l.] : University of Minnesota., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항212 p.
소장본 주기School code: 0130.
ISBN9780438169357
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
Adviser: Ping Wang.
요약As the most significant anthropogenic greenhouse gas, carbon dioxide emitted as an industrial pollution waste can be probably most effectively handled by the Carbon Capture and Storage (CCS) strategy. The energy efficiency of currently available
요약Among the numerous CO2-conversion and CO2-elution reaction pathways found in biology, the isocitrate dehydrogenase (ICDH) reaction in reductive tricarboxylic acid (RTCA) cycle was taken as our study model system due to its reversibility and agai
요약To enhance reaction kinetics, screening ideal enzyme and optimizing reaction condition were conducted. ICDH from Chlorobium limicola revealed the highest specific activity: 15.3 U/mg at pH 6 for carboxylation and 90.2 U/mg at pH 9 for decarboxyl
요약For carbon capture capacity, additional thermodynamic driving force can be created via designing of cascade reaction scheme. In this study, aconitase was introduced and isocitrate was further converted to citrate, lowing the overall Gibbs free e
요약Enzyme immobilization was conducted to improve system stability. During the process, 20~30 mg enzyme can be absorbed on 1 gram of mesoporous silicon foam (MSF) within 5 mins with the specific activity of decarboxylation in the order of 6 U per g
요약With economic analysis, the ICDH strategy can bring a 66% improvement in energy efficiency. The cost and stability of cofactor (NADPH) were the most significant barriers to the large-scale application of ICDH, mainly due to the poor stability of
요약This work demonstrates the feasibility of a novel carbon capture strategy applying reversible enzyme reactions. It reveals that reaction equilibrium can be effectively by manipulating pH and reaction pathways. The reaction intensity and stabilit
일반주제명Biochemistry.
Energy.
Chemical engineering.
언어영어
기본자료 저록Dissertation Abstracts International79-12B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T14998844

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