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Integrated Model Development for Safeguarding Pyroprocessing Facility

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개인저자Zhou, Wentao.
단체저자명The Ohio State University. Nuclear Engineering.
서명/저자사항Integrated Model Development for Safeguarding Pyroprocessing Facility.
발행사항[S.l.] : The Ohio State University., 2017
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2017
형태사항226 p.
소장본 주기School code: 0168.
ISBN9780438091610
일반주기 Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Advisers: Jinsuo Zhang
요약Pyroprocessing is an electrochemical method based on the molten salt electrolyte, mainly the LiCl-KCl eutectic molten salt, to recycle the used nuclear fuel. The key element of it is the electrorefining process, where the U, Pu, and minor actini
요약Present research focuses on the integrated model development for the separation processes in the pyroprocessing, including electrorefining, actinide drawdown, and rare earth drawdown. The main objective is to investigate the material transport p
요약U and Pu are the two main elements concerned in this study due to our interest in safeguards. Fundamental data of UCl3 in LiCl-KCl molten salt, namely activity coefficient, apparent potential, and diffusion coefficient, were calculated by molecu
요약The phase diagram of LiCl-KCl-PuCl3 was assessed by the CALPHAD method. It was found that the apparent potential also increases with the concentration. The solubility of PuCl3 in LiCl-KCl was determined to be 41.5 mol% at 773 K.
요약Integrating all these fundamental data with electrochemical theory, a kinetic model was developed to predict the material transport in the electrorefiner. After being validated by studies in literature, cases about electrorefining, actinide draw
일반주제명Nuclear engineering.
언어영어
기본자료 저록Dissertation Abstracts International79-10B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T15000223

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