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008181129s2017 ||| | | | eng d
020 ▼a 9780438091610
035 ▼a (MiAaPQ)AAI10871383
035 ▼a (MiAaPQ)OhioLINK:osu1492696274361015
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0491 ▼f DP
0820 ▼a 539.76
1001 ▼a Zhou, Wentao.
24510 ▼a Integrated Model Development for Safeguarding Pyroprocessing Facility.
260 ▼a [S.l.] : ▼b The Ohio State University., ▼c 2017
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2017
300 ▼a 226 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
500 ▼a Advisers: Jinsuo Zhang
5021 ▼a Thesis (Ph.D.)--The Ohio State University, 2017.
520 ▼a Pyroprocessing is an electrochemical method based on the molten salt electrolyte, mainly the LiCl-KCl eutectic molten salt, to recycle the used nuclear fuel. The key element of it is the electrorefining process, where the U, Pu, and minor actini
520 ▼a Present research focuses on the integrated model development for the separation processes in the pyroprocessing, including electrorefining, actinide drawdown, and rare earth drawdown. The main objective is to investigate the material transport p
520 ▼a U and Pu are the two main elements concerned in this study due to our interest in safeguards. Fundamental data of UCl3 in LiCl-KCl molten salt, namely activity coefficient, apparent potential, and diffusion coefficient, were calculated by molecu
520 ▼a The phase diagram of LiCl-KCl-PuCl3 was assessed by the CALPHAD method. It was found that the apparent potential also increases with the concentration. The solubility of PuCl3 in LiCl-KCl was determined to be 41.5 mol% at 773 K.
520 ▼a Integrating all these fundamental data with electrochemical theory, a kinetic model was developed to predict the material transport in the electrorefiner. After being validated by studies in literature, cases about electrorefining, actinide draw
590 ▼a School code: 0168.
650 4 ▼a Nuclear engineering.
690 ▼a 0552
71020 ▼a The Ohio State University. ▼b Nuclear Engineering.
7730 ▼t Dissertation Abstracts International ▼g 79-10B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0168
791 ▼a Ph.D.
792 ▼a 2017
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000223 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자 ▼b 관리자