| LDR | | 02313nmm uu200409 4500 |
| 001 | | 000000333824 |
| 005 | | 20240805174616 |
| 008 | | 181129s2018 |||||||||||||||||c||eng d |
| 020 | |
▼a 9780438126848 |
| 035 | |
▼a (MiAaPQ)AAI10903078 |
| 035 | |
▼a (MiAaPQ)umichrackham:001211 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
| 082 | 0 |
▼a 628 |
| 100 | 1 |
▼a Gebarski, Benjamin Bartholomew. |
| 245 | 14 |
▼a The Electronic and Atomic Structure of Actinide Contaminants at the Mineral-Fluid Interface. |
| 260 | |
▼a [S.l.] :
▼b University of Michigan.,
▼c 2018 |
| 260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
| 300 | |
▼a 175 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B. |
| 500 | |
▼a Adviser: Udo Becker. |
| 502 | 1 |
▼a Thesis (Ph.D.)--University of Michigan, 2018. |
| 520 | |
▼a Geochemical reactions at the mineral-water interface are a critical factor in the mobility of actinide contaminants such as those intrinsic to nuclear waste storage facilities. Actinides can undergo a number of sorption, phase, and oxidation sta |
| 520 | |
▼a In reducing conditions, soluble uranyl(VI) (UO22+) can be reduced to insoluble U(IV)O2 solid, resulting in the decrease of its mobility within the environment. Chapter 2 is an electrochemical investigation of U(VI) redox interactions in a relati |
| 520 | |
▼a Actinide contaminants such as uranyl peroxides can also be immobilized via redox or adsorption reactions catalyzed by mineral surfaces. Therefore Chapter 3 uses electrochemical atomic force microscopy (EC-AFM) in conjunction with spectroscopic m |
| 520 | |
▼a Actinides exceptionally mobile in aqueous conditions, such as pentavalent plutonyl (PuO2+), can be immobilized without a change in oxidation state via adsorption or incorporation into mineral hosts. Thus, Chapter 4 is a theoretical investigation |
| 590 | |
▼a School code: 0127. |
| 650 | 4 |
▼a Environmental science. |
| 690 | |
▼a 0768 |
| 710 | 20 |
▼a University of Michigan.
▼b Earth and Environmental Sciences. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 79-12B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0127 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2018 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000574
▼n KERIS |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a 관리자 |