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020 ▼a 9780438058446
035 ▼a (MiAaPQ)AAI10815056
035 ▼a (MiAaPQ)lehigh:11959
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0820 ▼a 660
1001 ▼a Wehrman, Matthew D.
24510 ▼a Rheological Properties of Colloidal and Polymeric Scaffolds Measured Using Multiple Particle Tracking Microrheology.
260 ▼a [S.l.] : ▼b Lehigh University., ▼c 2018
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2018
300 ▼a 215 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
500 ▼a Adviser: Kelly M. Schultz.
5021 ▼a Thesis (Ph.D.)--Lehigh University, 2018.
520 ▼a Characterizing the rheological properties of polymeric and colloidal gels during dynamic phase transitions is critical in developing targeted products for industrial and home care use. These materials require specific rheology that allow them to
520 ▼a We begin by characterizing the gelation of poly(ethylene glycol) (PEG) hydrogels at varying polymeric interactions and gelation mechanisms. The gels consist of a 20,000 g mol--1 4 arm star PEG backbone end-functionalized with either acrylate or
520 ▼a Microrheology is then used to measure the degradation and gelation of a fibrous colloidal gel, hydrogenated castor oil. HCO undergoes a heterogeneous phase transition based on an osmotic pressure gradient, making MPT an ideal measurement tool. T
520 ▼a To increase the amount of information gained from MPT experiments, we develop a technique to simultaneously track a bi-disperse population of probe particles. 0.5 and 2.0 microm particles are tracked separately using a brightness based radius of
520 ▼a To determine if colloidal rearrangement during phase transition is effecting the scaffold structure of HCO, a micro2rheology, microfluidics with microrheology, is developed. A two-layer microfluidic device is designed to exchange fluid surroundi
520 ▼a The effect of shear imparted on the sample during preparation is determined using a combination of microrheology, micro2rheology, and bulk rheology. (Abstract shortened by ProQuest.).
590 ▼a School code: 0105.
650 4 ▼a Chemical engineering.
650 4 ▼a Engineering.
690 ▼a 0542
690 ▼a 0537
71020 ▼a Lehigh University. ▼b Chemical Engineering.
7730 ▼t Dissertation Abstracts International ▼g 79-10B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0105
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T14998154 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자