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020 ▼a 9780438313200
035 ▼a (MiAaPQ)AAI10932267
035 ▼a (MiAaPQ)wisc:15673
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0491 ▼f DP
0820 ▼a 540
1001 ▼a Qiu, Yue.
24510 ▼a Modulation of Chemical Reactions by Glass Packing.
260 ▼a [S.l.] : ▼b The University of Wisconsin - Madison., ▼c 2018
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2018
300 ▼a 217 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
500 ▼a Adviser: Mark D. Ediger.
5021 ▼a Thesis (Ph.D.)--The University of Wisconsin - Madison, 2018.
520 ▼a Chemically stable solids are in demand for many applications, including pharmaceuticals and organic electronics. Previous efforts in crystals have established the importance of molecular packing in influencing chemical stability by comparing rea
520 ▼a Films of azobenzenes, photochromic molecules that can undergo trans to cis photoisomerization, were prepared by vapor-deposition at a wide range of substrate temperature. Photostability of vapor-deposited Disperse Orange 37, a push-pull azobenz
520 ▼a We further show that the enhanced photostability in vapor-deposited glasses is a general phenomenon by using a non-push-pull azobenzene, 4,4'-diphenyl azobenzene (DPA). By mixing DPA into the glass host of celecoxib, we directly measure populati
520 ▼a Additionally, to broaden the impact of vapor-deposition on chemical stability, we performed the solid-gas reaction of indomethacin with ammonia. Indomethacin has a carboxylic acid group that can react with ammonia to yield ammonium salt. In this
590 ▼a School code: 0262.
650 4 ▼a Chemistry.
690 ▼a 0485
71020 ▼a The University of Wisconsin - Madison. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 80-01B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0262
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15001090 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자 ▼b 관리자