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008181129s2017 ||| | | | eng d
020 ▼a 9780438165670
035 ▼a (MiAaPQ)AAI10906486
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0491 ▼f DP
0820 ▼a 660
1001 ▼a Cleveland, Christopher N.
24510 ▼a Corrosion of Copper in Deaerated Deionized Water and Geometry Induced Frequency Dispersion of the Ring Electrode.
260 ▼a [S.l.] : ▼b University of Florida., ▼c 2017
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2017
300 ▼a 111 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
5021 ▼a Thesis (Ph.D.)--University of Florida, 2017.
520 ▼a Copper is commonly regarded to be immune to corrosion in deaerated deionized electrolytes. The present work shows that, in the absence of hydrogen, copper will corrode on the order of 1 nm/day in deionized water with an O2 concentration on the o
520 ▼a An extended kinetic model is developed and used to study the cumulative corrosion rate of copper after 15 years for a microelectrode and for bulk copper. The parameters varied for this study were the area to volume ratio, copper and hydrogen mas
520 ▼a Simulations performed using a refined kinetic model for a microelectrode, validate the assumption that the hydrogen oxidation reaction can be neglected for the small electrode area to volume ratio and short times considered. The hydrogen oxidati
520 ▼a A 2-D axisymmetric mathematical model was developed to investigate frequency dispersion in a ring electrode. The finite element software COMSOL Multiphysics was used to solve Laplace's equation in cylindrical coordinates for the ring electrode w
590 ▼a School code: 0070.
650 4 ▼a Chemical engineering.
690 ▼a 0542
71020 ▼a University of Florida. ▼b Chemical Engineering.
7730 ▼t Dissertation Abstracts International ▼g 79-12B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0070
791 ▼a Ph.D.
792 ▼a 2017
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000764 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자 ▼b 관리자