| LDR | | 00000nmm u2200205 4500 |
| 001 | | 000000330998 |
| 005 | | 20241107152042 |
| 008 | | 181129s2018 ||| | | | eng d |
| 020 | |
▼a 9780438149557 |
| 035 | |
▼a (MiAaPQ)AAI10830791 |
| 035 | |
▼a (MiAaPQ)columbia:14794 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 248032 |
| 049 | 1 |
▼f DP |
| 082 | 0 |
▼a 546 |
| 100 | 1 |
▼a Champsaur, Anouck. |
| 245 | 12 |
▼a A Soft Chemistry Approach to Extended [Co6Se8] Materials. |
| 260 | |
▼a [S.l.] :
▼b Columbia University.,
▼c 2018 |
| 260 | 1 |
▼a Ann Arbor :
▼b ProQuest Dissertations & Theses,
▼c 2018 |
| 300 | |
▼a 184 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-11(E), Section: B. |
| 500 | |
▼a Adviser: Colin Nuckolls. |
| 502 | 1 |
▼a Thesis (Ph.D.)--Columbia University, 2018. |
| 520 | |
▼a This dissertation describes advances toward creating programmable building blocks and assembling them into new, tailored materials. I describe extended materials formed of bonded sets of cobalt selenide clusters. Rationally designed chemical tra |
| 520 | |
▼a The cobalt selenide clusters fundamental to this study are members of a larger class of clusters with the M6E8 core (M = metal, E = chalcogen). Chapter 1 introduces this family of clusters and reviews examples of previously made materials. |
| 520 | |
▼a Chapter 2 unveils a family of site-differentiated clusters, Co6 Se8(CO)x(PEt3)6-x, their substitution reactions, and assembly into bridged dimers and trimers. Electrochemical methods were used to investigate electronic coupling between the cores |
| 520 | |
▼a Chapter 3 introduces electrocrystallization as a method to synthesize extended, crystalline, solid state compounds from superatomic building blocks. By electrocrystallizing redox-active [Co6Se8] clusters with labile ligands in the presence of an |
| 520 | |
▼a Chapter 4 presents a metal coordination approach to [Co6Se 8] materials via reactive groups on the capping ligands. The redox-activity and multinuclearity of the superatom components creates a new level of complexity and synthetic sophistication |
| 520 | |
▼a Finally, Chapter 5 outlines a novel chemical transformation that dimerizes [Co6Se8] units to form a material with an expanded core, [Co12Se16], that exhibits electronic and optical properties distinct from the parent monomer. To accomplish this |
| 520 | |
▼a These chapters present novel synthetic approaches toward creating [Co 6Se8] materials with tuned dimensionality, size, and extensive charge delocalization. |
| 590 | |
▼a School code: 0054. |
| 650 | 4 |
▼a Inorganic chemistry. |
| 650 | 4 |
▼a Materials science. |
| 650 | 4 |
▼a Chemistry. |
| 690 | |
▼a 0488 |
| 690 | |
▼a 0794 |
| 690 | |
▼a 0485 |
| 710 | 20 |
▼a Columbia University.
▼b Chemistry. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 79-11B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0054 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2018 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T14999478
▼n KERIS |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a 관리자
▼b 관리자 |