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020 ▼a 9780438369078
035 ▼a (MiAaPQ)AAI10844910
035 ▼a (MiAaPQ)purdue:23223
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0820 ▼a 547
1001 ▼a Haskins, Chris William.
24510 ▼a Gas-Phase and Condensed-Phase Studies of Small Reactive Intermediates.
260 ▼a [S.l.] : ▼b Purdue University., ▼c 2018
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2018
300 ▼a 147 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
500 ▼a Adviser: Paul G. Wenthold.
5021 ▼a Thesis (Ph.D.)--Purdue University, 2018.
520 ▼a Nitriles are an integral functional group in many chemical industries. A new methodology for the dehydration of amides to nitriles has been developed using a palladium catalyst. The reaction conditions are robust and able to tolerate a wide var
520 ▼a Cyclopropanols are important precursors for the generation of beta-carbonyl radicals. In the presence of a single-electron oxidant, the beta-carbonyl radical can be generated and trapped. In this methodology, N-aryl acrylamides were used as a tr
520 ▼a Aryl Nitrenes are the other reactive intermediates of interest. Although extensively studied over the past 30 years, phenylnitrenes have a propensity for undergoing rearrangement reactions and forming polymeric tars. This is in direct contrast w
590 ▼a School code: 0183.
650 4 ▼a Organic chemistry.
690 ▼a 0490
71020 ▼a Purdue University. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 80-01B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0183
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000023 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자