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020 ▼a 9780438349681
035 ▼a (MiAaPQ)AAI10843084
035 ▼a (MiAaPQ)unc:18089
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 248032
0491 ▼f DP
0820 ▼a 547
1001 ▼a Carestia, Anthony Michael.
24510 ▼a Reagent-dictated Site Selective Hydrocarbon Functionalization Using Nitrogen-centered Radicals.
260 ▼a [S.l.] : ▼b The University of North Carolina at Chapel Hill., ▼c 2018
260 1 ▼a Ann Arbor : ▼b ProQuest Dissertations & Theses, ▼c 2018
300 ▼a 268 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
500 ▼a Advisers: Erik J. Alexanian
5021 ▼a Thesis (Ph.D.)--The University of North Carolina at Chapel Hill, 2018.
520 ▼a Chapter 1. Aliphatic C-H Functionalization: An overview of aliphatic radical C-H functionalization is presented with an emphasis on the challenge of site selectivity. Methods covered range from simple, unselective free radical halogenation to hi
520 ▼a Chapter 2. Reagent-Dictated Site-Selective C-H Chlorination: The development of a site-selective C-H chlorination is discussed. Primary site selectivity is achieved using highly hindered N-chloroamide reagent used. A computational study of the g
520 ▼a Chapter 3. Primary Selective C-H Functionalization of Polyolefins: A complementary method of polyolefin xanthylation was developed. The regioselectivity of the reaction favors 1째 functionalization over 2째 functionalization, in stark contrast to
590 ▼a School code: 0153.
650 4 ▼a Organic chemistry.
650 4 ▼a Chemistry.
690 ▼a 0490
690 ▼a 0485
71020 ▼a The University of North Carolina at Chapel Hill. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 80-01B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0153
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T14999897 ▼n KERIS
980 ▼a 201812 ▼f 2019
990 ▼a 관리자 ▼b 관리자