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Drying Inhomogeneity during Film Formation of Waterborne Latex Systems: A Mechanistic Study on Skin Layer Formation

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개인저자Huang, Hao.
단체저자명Lehigh University. Chemical Engineering.
서명/저자사항Drying Inhomogeneity during Film Formation of Waterborne Latex Systems: A Mechanistic Study on Skin Layer Formation.
발행사항[S.l.] : Lehigh University., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항252 p.
소장본 주기School code: 0105.
ISBN9780438058415
일반주기 Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Advisers: Mohamed S. El-Aasser
요약Drying inhomogeneity of latex is the phenomenon where the spatial distribution of latex particles is non-uniform and evolving with time during the drying process. In order to study this phenomenon, this dissertation research employed the optical
요약For the polystyrene model latex (with Tg = 106 째C), multiple types of drying inhomogeneity were observed at room temperature. Vertical packing and horizontal drying front were the packing processes of particles from the top of latex and the edge
요약For the film-forming low-Tg model latexes (acrylate copolymer latexes with Tg < 0 째C) at room temperature, the particles on the top of drying latex are readily deformed and coalesced early into a polymer layer (called "skin layer"). The low-perm
요약It is found that, the post-added (added after polymerization) surfactant into the low-Tg latex can delay the maturation of skin layer (Stage III), accelerate the increment of hcoal with time, and shorten the film drying time. A mechanism is prop
요약Drying inhomogeneity is complex, which is not only determined by the physical properties of latex, but also influenced by the water-soluble molecules and their molecular interactions. The OCT-Gravimetry-Video method can be a useful tool to study
일반주제명Chemical engineering.
Materials science.
Physics.
언어영어
기본자료 저록Dissertation Abstracts International79-10B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T14998139

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