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Mechanistic Studies into H2 Evolution and CO2 Reduction by Transition Metal Catalysts

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개인저자Schaugaard, Richard.
단체저자명Indiana University. Chemistry.
서명/저자사항Mechanistic Studies into H2 Evolution and CO2 Reduction by Transition Metal Catalysts.
발행사항[S.l.] : Indiana University., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항197 p.
소장본 주기School code: 0093.
ISBN9780438339460
일반주기 Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Krishnan Raghavachari.
요약The efficient production of chemical species relevant to energy storage and chemical feedstocks remains an essential and critical undertaking in modern chemistry and this thesis is concerned with theoretical investigations into these issues.
요약The first chapter explores the mechanism of catalytic electrochemical CO2 reduction by Re(L)(CO)3Cl, a complex containing a well-defined redox active nanographene ligand. A full mechanism was elucidated and the role of the nanographene ligand is
요약The second chapter concerns the mechanisms of three different small molecule MoS2 mimics, [Mo(PY5Me2)S2]2+, Mo(bpy)(S2)2(O), and [Mo2(S2) 6]2--, that are explored and contrasted. In the course of elucidating the mechanism of [Mo(PY5Me2)S2] 2+, t
요약The third and final chapter involves the gas phase hydrogen evolution reaction (HER) between mass selected MoxOy clusters with H2O and C2H4, the latter being present as a sacrificial reductant. Theory is used along with photoelectron spectroscop
일반주제명Chemistry.
언어영어
기본자료 저록Dissertation Abstracts International80-01B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T15001036

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