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Design of New Anion Exchange Membranes for Electrochemical Applications

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자료유형	E-Book
개인저자	Zhu, Liang.
단체저자명	The Pennsylvania State University. Materials Science and Engineering.
서명/저자사항	Design of New Anion Exchange Membranes for Electrochemical Applications.
발행사항	[S.l.] : The Pennsylvania State University., 2016
발행사항	Ann Arbor : ProQuest Dissertations & Theses, 2016
형태사항	189 p.
소장본 주기	School code: 0176.
ISBN	9780438136250
일반주기	Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
요약	Anion exchange membranes (AEMs) are polymer-based electrolyte solids that conduct anions (OH--, HCO3-- , Cl--, et al.), with positively charged groups bound covalently to the polymer backbones. There has been a strong and growing worldwide inter
요약	To produce anion conductive and durable polymer electrolytes for alkaline fuel cell applications, a series of cross-linked quaternary ammonium functionalized poly(2,6-dimethyl-1,4-phenylene oxide)s with mass-based ion exchange capacities (IEC) r
요약	Side-chain containing AEMs with one, two or three cations per side chain were designed and synthesized, enabling a study of how the degree of polymer backbone functionalization and arrangement of cations on the side chain impact AEM properties.
요약	Anion-conductive copolymers, poly(2,6-dimethyl-1,4-phenylene oxide)s containing fluorene side chains with pendant alkyltrimethylammonium groups, were synthesized via Suzuki-Miyaura coupling of aryl bromides with fluorene-boronic acids. The quate
요약	A unique approach was employed to toughen AEMs by crosslinking the AEMs using commercial Jeffamine additives. Compared to the BTMA40 membrane, the 10% Jeffamine cross-linked membrane demonstrated significantly higher elongation at break. To be s
요약	Overall, this thesis details a number of strategies for the large-scale production of PPO-based anion exchange membranes. These strategies will be useful in going forward in the design and deployment of hydroxide, bromide, bicarbonate, and chlor
일반주제명	Materials science. Polymer chemistry. Chemistry.
언어	영어
기본자료 저록	Dissertation Abstracts International79-12B(E). Dissertation Abstract International
대출바로가기	http://www.riss.kr/pdu/ddodLink.do?id=T15000755