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Efforts Toward Catalytic Methods Based on P(III)/P(V) Redox Cycling

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자료유형E-Book
개인저자Zhao, Wei.
단체저자명The Pennsylvania State University. Chemistry.
서명/저자사항Efforts Toward Catalytic Methods Based on P(III)/P(V) Redox Cycling.
발행사항[S.l.] : The Pennsylvania State University., 2016
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2016
형태사항341 p.
소장본 주기School code: 0176.
ISBN9780438136229
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
요약This dissertation describes efforts in the development of catalytic methods that are based on P(III)/P(V) redox cycling. Specifically, a catalytic oxygen atom transfer operating on P(III)/P(V)=O redox cycling and a reversible strong bond activat
요약Part I of the dissertation is focused on the development of a new type of phosphorus(III)-mediated carbonyl functionalization via the condensation of electron-deficient carbonyl compounds and nucleophilic trivalent phosphorus compounds (aka the
요약Part II of the dissertation extends the study on the effect of molecular geometry on reactivity. Through the design and synthesis of a new type of bicyclic phosphorous triamides with lower symmetry than canonical trivalent phosphorus compounds,
요약In pursuing catalysis based on P(III)/P(V) redox cycling, we have illustrated the power of alternating reactivity via manipulating molecular geometry on both kinetic and thermodynamic terms. The strategy of molecular geometric distortion in the
일반주제명Chemistry.
Inorganic chemistry.
Organic chemistry.
언어영어
기본자료 저록Dissertation Abstracts International79-12B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T15000753

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