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Synthesis, Shape, and Surfaces of Strontium and Barium Titanate Nanocrystals

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개인저자Crosby, Lawrence.
단체저자명Northwestern University. Materials Science and Engineering.
서명/저자사항Synthesis, Shape, and Surfaces of Strontium and Barium Titanate Nanocrystals.
발행사항[S.l.] : Northwestern University., 2018
발행사항Ann Arbor : ProQuest Dissertations & Theses, 2018
형태사항206 p.
소장본 주기School code: 0163.
ISBN9780438117112
일반주기 Source: Dissertation Abstracts International, Volume: 79-11(E), Section: B.
Adviser: Laurence D. Marks.
요약The atomic surfaces structures of shape-controlled oxide supports prepared hydrothermally result in nanocrystals for use as model catalysts to bridge the "materials gap" from studies on single crystals. SrTiO3 (001), (110), and BaTiO3 (001) surf
요약The Wulff shape of SrTiO3 was determined to be an octadecahedron with six {100} facets and twelve {110} facets. TEM measurements of the faceting ratios h110:h100 were found to agree well with surface energy ratios gamma110 :gamma100 derived fro
요약Using aberration-corrected HREM, the surface structure of {110}-faceted SrTiO3 nanoparticles synthesized solvothermally using glycerol as the surfactant yielded (n x 1) reconstructions with n=3 or 4. These structures are titania-rich and contain
요약Aberration-corrected HREM investigation of SrTiO3 nanocuboids made using caprylic acid, ethanol, and also BaTiO3 nanocuboids revealed that the (001) surfaces for all these nanoparticles are terminated with a TiO2 double layer. These results are
요약Pt and Pt deposited onto SrTiO3 nanopolyhedra were investigated by HREM to determine the stable Winterbottom construction.
요약The supported Pd particles were found to be predominantly multiply twinned particles while Pt particles were predominantly single crystals. The effects of sub-nanometer atomic layer deposition of films of titania and alumina are compared for the
요약Pt-SrTiO3 (110) catalyst samples prepared by ALD onto SrTiO 3 dodecahedra are compared with Pt-TiO2 catalysts prepared by ALD onto commercially purchased anatase TiO2. Catalytic testing of the CO oxidation reaction indicate that the turnover fre
일반주제명Materials science.
언어영어
기본자료 저록Dissertation Abstracts International79-11B(E).
Dissertation Abstract International
대출바로가기http://www.riss.kr/pdu/ddodLink.do?id=T14998409

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